ASTM E595

Konark Silicones

silicone products manufacturer

ASTM E595

ASTM E595 is a standard test method developed by ASTM International to evaluate the outgassing properties of materials in vacuum environments. This test is particularly important for applications where materials are exposed to high vacuum and can release volatile compounds that may condense on sensitive components, such as in space, aerospace, and electronics industries.

Key Details of ASTM E595

 

1. Purpose:

ASTM E595 is designed to measure the potential outgassing of materials under high vacuum. It specifically evaluates two main outgassing metrics:

  • Total Mass Loss (TML): The total percentage of mass a material loses when exposed to vacuum.
  • Collected Volatile Condensable Material (CVCM): The percentage of mass that condenses on a collector plate placed in proximity to the test sample.
 

2. Test Conditions:

  • The test is typically conducted in a vacuum environment at 125°C (257°F) for a duration of 24 hours.
  • The materials are placed in a vacuum chamber with a collector plate positioned to capture any volatile substances that are released from the material.
 

3. Acceptance Criteria:

  • For a material to pass the outgassing requirements commonly used in aerospace and similar fields, it should ideally meet the following thresholds:
  1. TML (Total Mass Loss) should be less than 1.0%.
  2. CVCM (Collected Volatile Condensable Material) should be less than 0.1%.
  • These criteria help ensure that materials used in sensitive environments will not outgas significant amounts of volatile substances that could interfere with electronics, optics, or other critical systems.
 

4. Application of Results:

  • Spacecraft and Satellites: NASA and other space agencies often require materials to pass ASTM E595 for use in spacecraft, as outgassing in space can contaminate sensitive equipment.
  • Electronics and Optics: In vacuum environments, volatile compounds from outgassing materials can condense on optical lenses or sensitive electronic components, affecting performance. Passing ASTM E595 ensures that materials are suitable for these applications.

How the Test is Conducted

 

  • The material is pre-weighed and then placed in a vacuum oven at the specified temperature and duration.
  • A collector plate is placed near the material sample to capture any volatiles that condense.
  • After the test, the material is re-weighed to determine the mass loss (TML), and the collector plate is analyzed to quantify any condensable volatiles (CVCM).

Importance of ASTM E595 Compliance

 

Passing ASTM E595 indicates that a material has low outgassing properties, which is crucial in environments where even minimal contamination could compromise the function of sensitive equipment. This standard is frequently referenced in industries that require stringent material performance, such as aerospace, defense, and high-performance electronics.

Critical mechanical properties of silicone rubber that are important, depending on the application. These include: 

1. Tensile Strength:

  • Definition: Tensile strength is the maximum stress that silicone rubber can withstand while being stretched before it breaks.
  • Description: For applications where silicone will experience pulling or stretching, such as seals, tubing, and diaphragms.

2. Elongation:

  • Definition: Elongation refers to the extent to which silicone rubber can be stretched before breaking, expressed as a percentage of its original length.
  • Description: This property measures the flexibility and stretchability of the silicone. High elongation is beneficial for applications requiring deformation without cracking or breaking, such as flexible gaskets, medical devices, and tubing. Silicone rubber typically exhibits excellent elongation, often ranging between 200% and 800%.

3. Hardness (Shore A):

  • Definition: Hardness measures the resistance of silicone rubber to indentation and is often indicated using the Shore A durometer scale.
  • Description: The Shore A hardness of silicone can range from very soft (as low as 10 Shore A) to very firm (up to 90 Shore A). Lower values indicate a softer, more flexible material, while higher values indicate a harder, more rigid material. This property helps determine how well the silicone can resist deformation under load and is crucial for choosing materials for cushioning, sealing, or structural support.

4. Tear Strength:

  • Definition: Tear strength is the resistance of silicone rubber to propagation of a cut or nick when it is under tension.
  • Description: It is measured in kilonewtons per meter (kN/m) or pounds per inch (ppi). A high tear strength means that silicone rubber can resist tearing forces, even if a small cut is present. This property is particularly important in applications where the material might be subject to sharp edges, flexing, or abrasive conditions, such as diaphragms, gaskets, and medical components that need to withstand frequent sterilization.

5. Compression Set:

The measure of a material’s ability to return to its original thickness after prolonged compressive stresses, which is particularly important in sealing applications.

6. Flexural Strength:

The ability of silicone to resist deformation under load, which is important for parts that will undergo repeated bending or flexing.

7. Resilience (Rebound):

The capacity of silicone to return energy upon deformation, which is relevant for dynamic applications like gaskets or vibration dampening.

8. Modulus of Elasticity:

Often referred to as Young’s modulus, this measures the stiffness of the silicone and its resistance to elastic deformation.

9. Fatigue Resistance:

The ability of silicone to withstand cyclic loading, important for applications involving repetitive motion or vibration.

10. Abrasion Resistance:

Resistance to surface wear or rubbing, crucial for components that are in contact with moving parts or experience friction.

11. Creep:

The tendency of silicone to deform under prolonged stress, which is relevant in load-bearing applications over time.

12. Impact Resistance:

The ability of silicone to absorb energy and resist shock, useful for components that may encounter sudden impacts.

13. Dynamic Mechanical Analysis (DMA):

This measures properties like viscoelastic behavior over a range of temperatures and frequencies, important for assessing performance under varying conditions.

 

These mechanical properties help determine how well silicone rubber performs under specific conditions and are crucial for selecting the appropriate formulation for an intended application.

Here’s a table summarizing the key mechanical properties of silicone rubber, along with their definitions, testing methods, and the relevant ASTM standards:

Mechanical Property Definition Testing Method ASTM Standard
Tensile Strength The maximum stress that silicone rubber can withstand while being stretched before breaking. A tensile test is conducted by stretching a specimen at a constant rate until it breaks, measuring the force applied and elongation. ASTM D412
Elongation The extent to which silicone rubber can be stretched before breaking, expressed as a percentage of its original length. Measured during the tensile test, calculating the change in length relative to the original length of the specimen. ASTM D412
Hardness (Shore A) The resistance of silicone rubber to indentation, using the Shore A durometer scale. A durometer is pressed into the silicone surface, and the resistance is measured to determine the hardness value. ASTM D2240
Tear Strength The resistance of silicone rubber to the propagation of a cut or nick when under tension. A specimen is prepared with a small notch and then stretched, with the force required to propagate the tear being measured. ASTM D624
Compression Set The measure of a material’s ability to return to its original thickness after prolonged compressive stress. A specimen is compressed to a specific percentage of its thickness for a set time and temperature, and the remaining deformation after release is measured. ASTM D395
Modulus of Elasticity The stiffness of silicone rubber and its resistance to elastic deformation. The modulus is calculated during a tensile test, by measuring the stress/strain ratio in the elastic deformation range. ASTM D412
Fatigue Resistance The ability of silicone rubber to withstand cyclic loading or repeated stress without failure. Silicone samples are repeatedly deformed or cycled to evaluate fatigue behavior over many cycles. ASTM D430 (specific to fatigue tests for elastomers)
Abrasion Resistance The ability of silicone to withstand surface wear or rubbing. Abrasion is evaluated by measuring weight loss or surface damage after rubbing against an abrasive surface. ASTM D5963
Compression Deflection The force required to compress a sample to a specific deflection, indicating stiffness under compression. Silicone is compressed, and the force required to achieve a defined deflection is measured. ASTM D575
Creep The tendency of silicone rubber to deform under prolonged load or stress. Specimens are subjected to a constant load over a defined period, and deformation is measured over time. ASTM D2990


These mechanical properties and their corresponding ASTM standards help characterize the performance of silicone rubber under various conditions, ensuring that the material meets the application-specific requirements and performs consistently.

At Konark, manufacturing silicone parts and components is our passion. Silicone rapid prototyping and silicone engineering is what we do best. Our goal is to take our customers from the silicone prototyping phase to high volume production in a robust, efficient and economical process.

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